Blacquiere Research GroupWestern Science

Publications

B, book chapter; C, communication; F,  full paper; P, patent; R, review

HQP supervised: Graduate Student; Undergraduate Student

F45. A.M.M. Beardall, D.E. Chapple, N. Henao Ruiz, P.D. Boyle, J.M. Blacquiere* Alkyne Hydroamination Inhibited by Vinylidene Deactivation, ChemCatChem, 2024, e202400407 graphical abstract

 

F44. E.S. Isbrandt, D.E. Chapple, N.T.P. Tu, V. Dimakos, A.M.M. Beardall, P.D. Boyle, C.N, Rowley,* J.M. Blacquiere,* and S.G. Newman* Controlling Reactivity and Selectivity in the Mizoroki-Heck Reaction: High Throughput Evaluation of 1,5-Diaza-3,7-diphosphacyclooctane Ligands, J. Am. Chem. Soc. 2024, 146, 5650

Graphical Abstract

F43. S. Kukendran, J.S. Lee, P.D. Boyle, J.M. Blacquiere* Ligand Redistribution Hinders Preparation of a Nickel(II)-Hydroxo, Can. J. Chem. 2024, ASAP

Graphical Abstract

R42. J.-W. Lamberink-Ilupeju, P.J. Ragogna*, J.M. Blacquiere* Hydrophosphorylation of C=O/N Bonds Using Organophosphine Oxides or Sulfides, Eur. J. Inorg. Chem. 2024, e202300444 Graphical Abstract

F42. J.-W. Lamberink-Ilupeju, M.J. Willans, J.B. Gilroy, J.J. Noël, J.M. Blacquiere*, P.J. Ragogna* Multicomponent Synthesis of Poly-a-Aminophosphine Chalcogenides and Subsequent Depolymerization, Inorg. Chem. 2023, 62, 15104.

graphical abstract

F41. M.B. Kindervater, V.N. Staroverov, K.M.K. Jackman, A.A. Fogh, L.S.G. Kelley, L. Lim, S. Sirohey, P.D. Boyle, J.M. Blacquiere* Operationally Unsaturated Ruthenium Complex Stabilized by a Phosphine 1-Azaallyl Ligand, Dalton Trans. 2023, 10744.

graphical abstract

F40. J.M. Stubbs, A.S. Nanuwa, M.D. Hoffman, J.M. Blacquiere* Catalyst Comparison for Additive-Free Acceptorless Dehydrogenation of Indoline Derivatives, Synlett, 2023, 34, 445.

Graphical Abstract

F39. J.-W. Lamberink, P.D. Boyle, J.B. Gilroy, J.J. Noël, J.M. Blacquiere*, P.J. Ragogna* Reactivity of Primary Phosphines and Primary Phosphine Sulfides toward Imines, Chem. Eur. J., 2022, 52

Graphical abstract

F38. D.E. Chapple, M.A. Hoffer, P.D. Boyle, J.M. Blacquiere* Alkyne Hydrofunctionalization Mechanism Including an Off-Cycle Alkoxycarbene Deactivation Complex, Organometallics, 2022, 41, 1532

graphical abstract

F37. K.M.K. Jackman, G. Liang, P.D. Boyle, P.M. Zimmerman*, J.M. Blacquiere* Changes in Ligand Coordination Mode Induce Bimetallic C-C Reductive Elimination, Dalton Trans. 2022, 51, 3977.

graphical abstract

F36. D.E. Chapple, P.D. Boyle, J.M. Blacquiere* Origin of Stability and Inhibition of Cooperative Alkyne Hydrofunctionalization Catalysts, ChemCatChem, 2021, 13, 3789graphical abstract

R35. J.M. Blacquiere* Structurally-Responsive Ligands for High-Performance Catalysts, ACS Catal., 2021, 11, 5416.  

F34. A. Behnia, M.A. Fard, J.M. Blacquiere*, R.J. Puddephatt*. Cycloneophylpalladium(IV) Complexes: Formation by Oxidative Addition and Selectivity of their Reductive Elimination Reactions, Organometallics, 2020, 39, 4037 graphical abstract

C33. S. Hajirahimkhan, D.E. Chapple, G. Gholami, J.M. Blacquiere, C. Xu* and P.J. Ragogna* “Lignophines”: Lignin-Based Tertiary Phosphines with Metal-Scavenging Ability, Chem. Commun., 2020, 56, 10357

C32. B.J. Bridge, P.D. Boyle, J.M. Blacquiere* endo-Selective Iron Catalysts for Intramolecular Hydrofunctionalization of Alkynes, Organometallics, 2020, 39, 2570

graphical abstract

F31. J.M. StubbsB.J. Bridge, J.M. Blacquiere* Optimizing Ligand Structure for Low-Loading and Fast Catalysis for Alkynyl-Alcohol and -Amine Cyclization. Dalton Trans., 2019, 48, 7928 graphical abstract

C30. K.M.K. Jackman, B.J. BridgeE.R. Sauvé, C.N. Rowley, C.H.M. Zheng, J.M. Stubbs, P.D. Boyle, J.M. Blacquiere*. C(sp3)-C(sp3) Coupling with a Pd(II) Complex Bearing a Structurally Responsive Ligand. Organometallics, 2019, 38, 1677graphical abstract

F29. K.M.K. Jackman, A.A. Fogh, J.M. Stubbs, J.M. Blacquiere*. Synthesis of Pd Phosphine-Imine Complexes and their Reactivity with Base. J. Organomet. Chem., 2019, 880, 56. Special Issue: in Honour of R.J. Puddephatt’s 75th Birthdaygraphical abstract

F28. J.M. Stubbs, D.E. Chapple, P.D. Boyle, J.M. Blacquiere* 'Catalyst Pendent-Base Effects on Cyclization of Alkynyl Amines' ChemCatChem, 2018, 10, 4001.

 graphical abstract

F27. A. Behnia, M.A. Fard, J.M. Blacquiere,* R.J. Puddephatt * 'Mild and Selective Pd-Ar Protonolysis and C-H Activation Promoted by a Ligand Aryloxide Group' Dalton Trans., 2018, 47, 3538.

 graphical abstract

F26. Z. Ding, J.M. Stubbs, D. McRae, J.M. Blacquiere, F. Lagugne-Labarthet, S. Mittler* 'A Mass-Producible and Versatile Sensing System: Localized Surface Plasmon Resonance Excited by Individual Waveguide Modes' ACS Sens., 2018, 3, 334.

F25. A. Behnia, M.A. Fard, J.M.Blacquiere*, R.J. Puddephatt* ‘Reactivity of a Palladacycle Complex: A Monodentate Carbonate Complex and the Remarkable Selectivity and Mechanism of a Neophyl Rearrangement’ Organometallics, 2017, 36, 4759. 

graphical abstract

F24. R.J. Hazlehurst, S.W.E. Hendriks, P.D. Boyle, J.M. Blacquiere* ‘Ligand Dynamics and Aerobic Allylic Oxidation with Bifunctional Ni(NHC) ComplexesChemistrySelect, 2017, 2, 6732.

                                      graphical abstract 

C23. T.J. Cuthbert, E. Evoy, J.P.J. Bow, R. Guterman, J.M. Stubbs, E.R. Gillies, P.J. Ragogna*, J.M. Blacquiere* ‘CapturePhos – A Phosphorus-Rich Polymer as a Homogeneous Catalyst ScavengerCatal. Sci. Tech., 2017, 2685.

graphical abstract

F22. J.M. Stubbs, R.J. Hazlehurst, P.D. Boyle, J.M. Blacquiere* ‘Acceptorless Dehydrogenation of Amines with Ru(PR2NR'2) and Ru(dppp) ComplexesOrganometallics, 2017, 36, 1692.

C21. J.M. Stubbs, K.F. Firth, B.J. Bridge, K.J. Berger, R.J. Hazlehurst, P.D. Boyle, J.M. Blacquiere* ‘Phosphine-Imine and -Enamido Ligands for Acceptorless Dehydrogenation CatalysisDalton Trans., 2017, 46, 647.

                                          graphical abstract

F20. A. Behnia, P.D. Boyle, Mahmood A. Fard, J.M.Blacquiere*, R.J. Puddephatt* ‘Pincer-Plus-One Ligands in Self-Assembly with Palladium(II):  A Molecular Square and a Molecular TetrahedronDalton Trans., 2016, 45, 19485 

Graphical Abstract

C19. J.M. Stubbs, J.-P.J. Bow, R.J. Hazlehurst, J.M. Blacquiere* 'Catalytic Cyclization and Competitive Deactivation with Ru(PR2NR'2) Complexes' Dalton Trans., 2016, 45, 17100.

Graphical Abstract for C19

F18. A. Behnia, P.D. Boyle, J.M. Blacquiere*, R.J. Puddephatt* 'Selective Oxygen Atom Insertion into an Aryl-Palladium Bond' Organometallics, 2016, 35, 2645.

graphical abstract

C17. J.P.J. Bow, P.D. Boyle, J.M. Blacquiere*. ‘Substrate-Mediated Deactivation of a Ru(PtBu2NBn2) Cooperative ComplexEur. J. Inorg. Chem., 2015, 4162.

graphical abstract

Pre-UWO

F16. J.M. Blacquiere*, M.L. Pegis, S. Raugei, W. Kaminsky, A. Forget, S.A. Cook, T. Taguchi, J.M. Mayer*. 'Synthesis and Reactivity of Tripodal Complexes Containing Pendant Bases' Inorg. Chem., 2014, 53, 9242.

F15. J.M. Blacquiere, C.S. Higman, R. McDonald, D.E. Fogg*. ‘A Reactive Ru-Binaphtholate Building Block with Self-Tuning HapticityJ. Am. Chem. Soc., 2011, 133, 14054.

C14. J.M. Blacquiere, C.S. Higman, S.I. Gorelsky, N.J. Beach, S. Dalgarno, D.E. Fogg*. 'Unusually Strong Binding of Dinitrogen at Ruthenium' Angew. Chem. Int. Ed., 2011, 50, 916.

F13. S. Monfette, J.M. Blacquiere, D.E. Fogg*. 'The Future, Faster: Roles for High-Throughput Experimentation in Accelerating Discovery in Organometallic Chemistry and Catalysis' Organometallics, 2011, 30, 36. 

C12. J.M. Blacquiere, R. McDonald, D.E. Fogg*. 'Integrating the Schrock and Grubbs Catalysts: Ruthenium-Binaphtholate Catalysts for Olefin MetathesisAngew. Chem. Int. Ed., 2010, 49, 3807.

F11. N.J. Beach, J.M. Blacquiere, S.D. Drouin, and D.E. Fogg*. 'Carbonyl-Amplified Catalyst Performance: Balancing Stability against Activity for Five-Coordinate Ruthenium Hydride Hydridocarbonyl ComplexesOrganometallics, 2009, 28, 441.

P10. J.M. Blacquiere, R.T. Baker and R.J. Keaton. 'Base Metal Catalyzed Dehydrogenation of Ammonia-Borane for Chemical Hydrogen Storage' U.S. Patent, 7,544,837, Issued, 2009; filed, 2006.

C9. J.M. Blacquiere, T. Jurca, J. Weiss, D.E. Fogg*. 'Time as a Dimension in High-Throughput Homogeneous CatalysisAdv. Synth. Catal., 2008, 350, 2849.

F8. D.R. Duguay, M.T. Zamora, J.M. Blacquiere, F.E. Appoh, C.M. Vogels, S.L. Wheaton, F.J. Baerlocher, A. Decken, S.A. Westcott. ‘Synthesis, Characterization and Antifungal Testing of 3,4-dihydropyrimidin-2(1H)-(thio)ones Containing Boronic Acids and Boronate EstersCent. Eur. J. Chem., 2008, 562.

C7. M.D. Eelman, J.M. Blacquiere, M.M. Moriarty, D.E. Fogg*. 'Retooling MALDI Mass Spectrometry for Organotransition-Metal CatalysisAngew. Chem. Int. Ed. 2007, 47, 303. (VIP)

F6. J.D. Webb, D.J. Harrison, D.W. Norman, J.M. Blacquiere, C.M. Vogels, A. Decken, C.G. Bates, D. Venkataraman, R.T. Baker*, S.A. Westcott*. 'Metal Catalyzed Hydroboration of Vinyl Sulfides, Sulfoxides, Sulfones, and SulfonatesJ. Mol. Cat. A, 2007, 275, 91.

B5. S. Monfette, J.M. Blacquiere, J.C. Conrad, N.J. Beach, D.E. Fogg* 'Ru-Aryloxide Catalysts for Olefin Metathesis' in Metathesis Chemistry: From Nanostructure Design to Synthesis of Advanced Materials, NATO Science Series II, Vol 243, Y. Imamoglu, V. Dragutan, Eds.  Springer Verlag, Berlin, 2007, p. 79-89.

C4. R.J. Keaton, J.M. Blacquiere, R.T. Baker*. “Base Metal Catalyzed Dehydrogenation of Ammonia-Borane for Chemical Hydrogen StorageJ. Am. Chem. Soc. 2007, 129, 1844. (Hot Paper)

C3. A. Decken, J.M. Blacquiere, C.M. Vogels, S.A. Westcott* 'N-[(Benzyl­carbamo­yl)(phen­yl)meth­yl]-N-[3-(4,4,5,5-tetra­methyl-1,3,2-dioxaborolan-2-yl)phen­yl]benzamideActa. Cryst. 2006, E62, o2207.

F2. J.M. Blacquiere, O. Sicora, C.M. Vogels, M. Cuperlovic-Culf, A. Decken, R.J. Ouellette and S.A. Westcott*. 'Dihydropyrimidinones Containing Boronic AcidsCan. J. Chem. 2005, 83, 2052 (2005).

F1. R.R. Coombs, M.K. Ringer, J.M. Blacquiere, J.S. Neilsen, J.C. Smith, Y-S. Uh, H. Zhang, J.B. Gilbert, L.J. Leger, A.M. Irving, S.L. Wheaton, F.J. Baerlocher, C.M. Vogels, A. Decken and S.A. Westcott*. 'Palladium (II) Schiff Base Complexes Derived from Sulfanilamides and AminobenzothiazolesTrans. Met. Chem. 2005, 30, 411.