*Invited Concept Article.
75. Maar, R.R.; Catingan, S.D.; Staroverov, V.N.;  Gilroy, J.B.* Formazanate Complexes of Hypervalent Group-14 Elements as Precursors to Electronically Stabilized Radicals. Angew. Chem. Int. Ed. 2018, 57, 9870-9874link
74. Dhindsa, J.S.; Maar, R.R.; Barbon, S.M.; Olivia Aviles, M.; Powell, Z.K.; Lagugne-Labarthet, F.;  Gilroy, J.B.* A pi-Conjugated Inorganic Polymer Contructed from Boron Difluoride Formazanates and Platinum(II) Diynes. Chem. Commun. 2018,54, 6899-6902link


Recent Publications

65. Barbon, S.M.; Novoa, S.; Bender, D.; Groom, H.; Luyt, L.G.*; Gilroy, J.B.* Copper-Assisted Azide-Alkyne Cycloaddition Chemistry as a Tool for the Production of Emissive Boron Difluoride 3-Cyanoformazanates. Org. Chem. Front. 2017, 4, 178-190link
64. Colomba, A.; Biesinger, M.C.; Divigalpitiya, R.; Brandys, F.A.; Gilroy, J.B.* Dye Rejection Membranes Prepared from Oxidized Graphite Particles. Can. J. Chem. 2017, 95, 1103-1109link
*Invited contribution to special issue in honour of the career of Prof. T.K. Sham.
66. Paquette, J.A.; Rabiee Kenaree, A.; Gilroy, J.B.* Metal-Containing Polymers Bearing Pendant Nickel(II) Complexes of Goedken's Macrocycle. Polym. Chem. 2017, 8, 2164-2172link
67. Rabiee Kenaree, A.; Gilroy, J.B.* A Phosphine-Based Heterotrimetallic (M = Fe, Ru, W) Homopolymer. Organometallics 2017,36, 2483-2486link
*Invited contribution to special issue: Tailoring the Optoelectronic Properties of Organometallic Compounds with Main Group Elements.
71. Barbon, S.M.; Staroverov, V.N.; Gilroy, J.B.* Structurally Diverse Boron-Nitrogen Heterocycles from an (N2O2)3- Formazanate Ligand. Angew. Chem. Int. Ed. 2017, 56, 8173-8177link
68. Novoa, S.; Gilroy, J.B.* (Co)polymers Containing Boron Difluoride 3-Cyanoformazanate Complexes: Emission Enhancement via Random Copolymerization. Polym. Chem. 2017, 8, 5388-5395link
69. Barbon, S.M.; Buddingh, J.V.; Maar, R.R.; Gilroy, J.B.* Boron Difluoride Adducts of a Flexidentate Pyridine-Substituted Formazanate Ligand: Property Modulation via Protonation and Coordination Chemistry. Inorg. Chem. 2017, 56, 12003-12011link
70. Maar, R.R.; Rabiee Kenaree, A.; Zhang, R.; Tao, Y.; Katzman, B. D.; Staroverov, V.N.; Ding, Z.; Gilroy, J.B.* Aluminum Complexes of (N2O2)3- Formazanate Ligands Supported by Phosphine Oxide Donors. Inorg. Chem. 2017, 56, 12436-12447link
72. Hesari, M.; Barbon, S.M.; Mendes, R.B.; Staroverov, V.N.; Ding, Z.*; Gilroy, J.B.* Structural Tuning of Boron Difluoride Formazanate Electrochemiluminescence Mediated by Tri-n-propylamine. J. Phys. Chem. C 2018, 122, 1258-1266link
73. Maar, R.R.; Gilroy, J.B.* Group 13 Complexes of Chelating (N2O2)n- Ligands as Hybrid Molecular Materials. Chem. Eur. J. 2018, 24, 12449-12457link


*Invited contribution to Emerging Investigators Issue 2018
76. Charlton, G.D.; Barbon, S.M.; Gilroy, J.B.*; Dyker, C.A.* A Bipolar Verdazyl Radical for a Symmetric All-Organic Redox Flow-Type Battery. J. Energy Chem. 2019, 34, 52-56link
77. Wang, Z.; Paquette, J.A.; Staroverov, V.N.; Gilroy, J.B.*; Sham, T.-K.* X-Ray Absorption Near-Edge Structure Spectroscopy of a Stable 6-Oxoverdazyl Radical and Its Diamagnetic Precursor. J. Phys. Chem. A 2019, 123, 323-328link
79. Farhadpour, B.; Guo, J.; Hairsine, D.W.; Gilroy, J.B.; Baines, K.M.* On the Primary Structure of Polysilenes and Polygermenes. Polym. Chem. 2019, 10, 4887-4894link
82. Maar, R.R.; Zhang, R.; Stephens, D.G.; Ding, Z.*; Gilroy, J.B.* Near-Infrared Photoluminescence and Electrochemiluminescence from a Remarkably Simple Boron Difluoride Formazante Dye. Angew. Chem. Int. Ed. 2019, 58, 1052-1056link
80. Cappello, D.; Therien, D.A.B.; Staroverov, V.N.; Lagugne-Labarthet, F.; Gilroy, J.B.* Optoelectronic, Aggregation, and Redox Properties of Double-Rotor Boron Difluoride Hydrazone Dyes. Chem. Eur. J. 2019, 25, 5994-6006link
*Featured as an Angew. Chem. Int. Ed. spotlight article.
81. Maar, R.R.; Hoffman, N.A.; Staroverov, V.N.; Gilroy, J.B.* Oxoborane Formation Turns on Formazanate-Based Photoluminescence. Chem. Eur. J. 2019, 25, 11015-11019link
78. Van Belois, A.; Maar, R.R.; Workentin, M.S.*; Gilroy, J.B.* Dialkynylborane Complexes of Formazanate Ligands: Synthesis, Electronic Properties, and Reactivity. Inorg. Chem. 2019, 58, 834-843link
83. Melenbacher, A.; Dhindsa, J.S.; Gilroy, J.B.*; Stillman, M.J.* Unveiling the Hidden, Dark, and Short Lifetime of a Vibronic State in a Boron Difluoride Formazanate Dye. Angew. Chem. Int. Ed. 2019, 58, 15339-15343link
86. Dhindsa, J.S.; Melenbacher, A.; Barbon, S.M.; Stillman, M.J.; Gilroy, J.B.* Altering the Optoelectronic Properties of Boron Difluoride Formazanate Dyes via Conjugation with Platinum(II)-Acetylides. Dalton Trans. 2020, 49, 16133-16142link
*Invited contribution to special issue: New Talent: Americas 2020.
*Highlighted by Advances in Engineering.
85. Anghel, M.; Magnan, F.; Catingan, S.D.; McCready, M.A.; Aawani, E.; Wong, V.; Singh, D.; Fanchini, G.*; Gilroy, J.B.*Redox Polymers Incorporating Pendant 6-Oxoverdazyl and Nitronyl Nitroxide Radicals. J. Polym. Sci. 2020, 58, 309-313link
89. Gilroy, J.B.*; Otten, E.* Formazanate Coordination Compounds: Synthesis, Reactivity, and Applications. Chem. Soc. Rev. 2020, 49, 85-113link